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Abstract The central regions of the Milky Way constitute a unique laboratory for a wide swath of astrophysical studies; consequently, the inner ∼400 pc have been the target of numerous large surveys at all accessible wavelengths. In this paper, we present a catalog of sources at 25 and 37μm located within all of the regions observed with the SOFIA/FORCAST instrument in the inner ∼200 pc of the Galaxy. The majority of the observations were obtained as part of the SOFIA Cycle 7 Galactic Center Legacy program survey, which was designed to complement the Spitzer/MIPS 24μm catalog in regions saturated in the MIPS observations. Due to the wide variety of source types captured by our observations at 25 and 37μm, we do not limit the FORCAST source catalog to unresolved point sources, or treat all sources as if they are pointlike sources. The catalog includes all detectable sources in the regions, resulting in a catalog of 950 sources, including point sources, compact sources, and extended sources. We also provide the user with metrics to discriminate between the source types. 

Similarities and differences of halogen and hydrogen bonding were explored via UV–Vis and 1H NMR measurements, X-ray crystallography and computational analysis of the associations of CHX3 (X=I, Br, Cl) with aromatic (tetramethyl-p-phenylenediamine) and aliphatic (4-diazabicyclo[2,2,2]octane) amines. When the polarization of haloforms was taken into account, the strengths of these complexes followed the same correlation with the electrostatic potentials on the surfaces of the interacting atoms. However, their spectral properties were quite distinct. While the halogen-bonded complexes showed new intense absorption bands in the UV–Vis spectra, the absorptions of their hydrogen-bonded analogues were close to the superposition of the absorption of reactants. Additionally, halogen bonding led to a shift in the NMR signal of haloform protons to lower ppm values compared with the individual haloforms, whereas hydrogen bonding of CHX3 with aliphatic amines resulted in a shift in the opposite direction. The effects of hydrogen bonding with aromatic amines on the NMR spectra of haloforms were ambivalent. Titration of all CHX3 with these nucleophiles produced consistent shifts in their protons’ signals to lower ppm values, whereas calculations of these pairs produced multiple hydrogen-bonded minima with similar structures and energies, but opposite directions of the NMR signals’ shifts. Experimental and computational data were used for the evaluation of formation constants of some halogen- and hydrogen-bonded complexes between haloforms and amines co-existing in solutions.